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Qualitative Band Diagram of Intrinsic and Extrinsic Materials

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Probablity Distribution Function

Electrons are fermions, which satisfy the exclusion principle. So, it maintains the Fermi-Dirac distribution. Where, K is Boltzmann’s constant. K=1.38×10 -23 J/K Or K=8.62×10 -5 eV/K T is absolute temperature. E F is Fermi level. Let, E=E F So that, f(E)= ½ So E F is the Fermi energy level at which the PDF is ½ . If T=0K the distribution takes the simple rectangular, shown in figure.

Intrinsic & Extrinsic Materials

Intrinsic Material: The material in which the electron and the hole concentration are same, is known as intrinsic material. Electron concentration, n o = Hole concentration, p o Electron concentration, n i = Hole concentration, p i Extrinsic Material: The carrier concentration (no & po) are not same i.e. they differes from intrinsic concentration (ni & pi), is known as extrinsic material. Electron concentration, n o ≠ Hole concentration, p o Electron concentration, n i ≠ Hole concentration, p i Also n i ≠ n o and p o ≠ n i